无机化学物质的命名.ppt

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1、无机化合物的命名,Nomenclature of Inorganic Chemicals,element,compound,一.元素和单质的命名,“元素”和“单质”的英文意思都是“element”，有时为了区别，在强调“单质”时可用“free element or elementary substance”。因此，单质的英文名称与元素的英文名称是一样的。下面给出的既是元素的名称，同时又是单质的名称。,S-block Element(S区元素),IAHydrogen(H)Lithium(Li)Sodium(Na)Potassium(K)Rubidium(Ru)Cesium(Ce)Francium

2、(Fr),IIABeryllium(Be)Magnesium(Mg)Calcium(Ca)Strontium(Sr)Barium(Ba)Radium(Ra),P26,III A boron(B)Aluminium(Al)Gallium(Ga)Indium(In)Thallium(Tl),IV A Carbon(C)Silicon(Si)Germanium(Ge)Tin(Sn)Lead(Pb)plumbi,V A Nitrogen(N)Phosphorus(P)Arsenic(As)antimony(Sb)Bismuth(Bi),VIA oxygen(O)sulfur(S)Selenium(Se

3、)Tellurium(Te)Polonium(Po),VIIA fluorine(F)Chlorine(Cl)Bromine(Br)Iodine(I)Astatine(At),0 Helium(He)Neon(Ne)argon(Ar)Krypton(Kr)Xenon(Xe)Radon(Ra),P-block Element(P区元素),Common Transition Elememt,Fe:iron;determine Mn:manganese Cu:copper;cuprum Zn:zinc;spelter Hg:mercury;quicksilver Ag:silver;argentin

4、e Au:gold;aurum,二.化合物的命名,化合物的命名顺序都是根据化学式从左往右读，这与中文读法顺序是相反的。表示原子个数时使用前缀：(1)mono-,(2)di-,(3)tri-,(4)tetra-,(5)penta-，(6)hexa-,(7)hepta-,(8)octa-,(9)nona-,(10)deca-，但是在不会引起歧义时，这些前缀都尽 可能被省去。,monovalent:单价的 carbon dioxane:CO2tribromethane:CHBr3;tetrachloromethane:CCl4 CO(Carbon monoxide)NO(Nitrogen oxide

5、)NO2(Nitrogen dioxide)N2O3(Nitrogen trioxide)N2O5(Nitrogen pentoxide)N2O(nitrous oxide)FeO(Ferrous oxide),Fe2O3(Ferric oxide);MnO(Manganous oxide)Mn2O3(Manganic oxide),H2MnO4(Manganic acid)MnO2(Manganese dioxide),VB:valence bond theoryMO:molecular orbital theory,1.化合物正电荷部分的读法,1.1 Single valence ions

6、 Cations name=Element for example:Na+Sodium Al3+Aluminum K+Potassium Ca2+Calcium 如:CO:carbon monoxide Al2O3:aluminium oxide N2O4：Dinitrogen tetroxide(tetra-,mono-后缀中的a,o在后-o之前省去),ion:离子anion：阴离子cation:阳离子,1.2 Multivalence ions,Cations name=Element(N)For example:Fe2+Iron(II)or Ferrous Fe3+Iron(III)or

7、 Ferric Cr2+Chromium(II)Cr3+Chromium(III)Mn4+Manganese(IV)Mn2+Manganese(II),2.化合物负电荷部分的读法,2.1 Monatomic anions Anions name=Elements root-ide For example:Cl-Chloride O2-Oxide Br-Bromide OH-Hydroxide I-Iodide CN-Cyanide S2-Sulfide H-Hydride,2.2 Polyatomic oxyanions,2.2.1 Acid radicals for normal salt(

8、正酸根-ate)Anions name=Central Elements root-ate For example:ClO3-Chlorate IO3-Iodate PO43-Phosphate NO3-Nitrate SO42-Sulfate CO32-Carbonate,2.2.2 Acid radicals for hypo-salts(次酸根-ite),Anions name=Hypo-Central elements root-ite For example:ClO-Hypochlorite IO-Hypoiodite PO23-Hypophosphite,2.2.3 Acid ra

9、dicals for persalts(高酸根Per-ate),Anions name=Per-Central Elements root-ate For example:ClO4-Perchlorate IO4-Periodate MnO4-Permanganate,2.2.4 含氧酸与含氧酸根阴离子,采用前后缀的不同组合显示不同价态的含氧酸和含氧酸根阴离子，价态相同的含氧酸及含氧酸根阴离子具有相同的前缀，不同的后缀。高某酸 per-ic 正酸 ic 亚酸-ous 次酸 hypo-ous 高某酸根 per-ate 正酸根 ate 亚酸根-ite 次酸根hypo-ite 其它的前缀还有 ort

10、ho-正 meta-偏 thio-硫代举例：HClO4 perchloric acid ClO4-perchlorate ion HClO3 chloric acid ClO3-chlorate ion HClO2 chlorous acid ClO2-chlorite ion HClO hypochlorous acid ClO-hypochlorite ion H2SO4 sulfuric acid H2SO3 sulfurous acid HNO3 nitric acid HNO2 nitrous acid HPO3 metaphosphoric acid S2O32-thiosulfa

11、te ion,3.Naming compounds,3.1 Metal oxide Metal oxide=Cation+oxide For example:FeO Iron(II)oxide(Ferrous oxide)Fe2O3 Iron(III)oxide(Ferric oxide)Fe3O4 Ferroferric oxide Pb3O4 Trilead tetroxide Na2O2 Sodium peroxide,Nonmetal oxide=n-Nonmetal element+n-oxide For example:CO Carbon monoxide CO2 Carbon d

12、ioxide SO3 Sulfur trioxide N2O3 Dinitrogen trioxide P2O5 Diphosphorus pentoxide N2O4 Dinitrogen tetroxide(tetra-,mono-后缀中的a,o在后一o之前省去)有些物质常用俗称,如NO:nitric oxide N2O:nitrous oxide,3.2 Nonmetal oxide,4.非金属氢化物,除了水和氨气使用俗称water，ammonia以外，其它的非金属氢化物都用系统名称，命名规则根据化学式的写法不同而有所不同。4.1 对于卤族和氧族氢化物，H在化学式中写在前面，因此将其看成

13、与另一元素的二元化合物。举例：HF hydrogen fluoride HCl hydrogen chloride HBr hydrogen bromide HI hydrogen iodide H2S hydrogen sulfide H2Se hydrogen selenide H2Te hydrogen telluride,4.2 对于其它族的非金属氢化物，在化学式中写在后面，可加后缀-ane，氮族还可加-ine。举例：PH3:phosphine或phosphane AsH3:arsine或arsane SbH3:stibine或stibane BiH3:bismuthane CH4:m

14、ethane SiH4:silane B2H6:diborane NH3:ammonia,5.无氧酸,命名规则：hydro-词根-icacid 举例：HCl:hydrochloric acid H2S:hydrosulfuric acid HF:hydrofluoric acid HBr:hydrobromic aicd,总结:,H2SO4（+6）Sulfuric acid(正),H2SO3（+4）sulfurous acid;(亚),H2SO5 Peroxy sulfuric,（过）,H2SO7（+6）Pyro sulfuric,acid)(焦),H2S2O3(Thiosulfuric ac

15、id）e.g.Na2S2O3（硫代）,-H2O,-O-O-,-O,S O,HPO3（偏）(Meta phosphoric,),H3PO4(正)(Phosphoric,),H3PO3（亚）(Phosphorous,),H3PO2(次)(Hypo-phosphorous,),H4P2O7(焦)(Pyro phosphoric,),分子间-H2O,分子内-H2O,-O,-O,+5,+3,+1,H3BO3(Ortho boric,)(原);,HClO(Hypochlorous acid)(次),HClO3(Chloric acid)(正),HClO4(Perchloric acid)(高),HClO2

16、(Chlorous acid)(亚),-O,-O,-O,+5,+7,+3,+1,6.Bases,Base=Metal cation+hydroxide For example:Al(OH)3 Aluminum hydroxide NaOH Sodium hydroxide Ca(OH)2 Calcium hydroxide Ba(OH)2 Barium hydroxide Co(OH)2 Cobalt(II)hydroxide,7.盐(Salts),7.1正盐(Normal salt)：根据化学式从左往右分别读出阳离子和阴离子的名称。Normal salt=Cation+anion For e

17、xample:HgSO4 Mercury(II)sulfate Hg2SO4 Mercury(I)sulfate KNO3 Potassium nitrate Na2CO3 Sodium carbonate NaClO Sodium hypochlorite FeSO4 iron(II)sulfate KMnO4 potassium permanganate,7.2 酸式盐：(Acidic salts)同正盐的读法，酸根中的读做hydrogen，氢原子的个数用前缀表示。,Acidic salt=Cation+hydrogen+anion For example:NaHSO4 Sodium hy

18、drogen sulfate Na2HPO4 Disodium hydrogen phosphate NaH2PO4 Sodium dihydrogen phosphate Ca(HSO4)2 Calcium bisulfate NaHCO3 Sodium hydrogencarbonate 或 Sodium bicarbonate,7.3 Basic salts,Basic salt=Cation+hydroxy-anion For example:Cu2(OH)2CO3:Dicopper(II)dihydroxycarbonate Ca(OH)Cl:Calcium hydroxychlor

19、ide Mg(OH)PO4:Magnesium hydroxyphosphate,7.4 复盐(Mixed salts)：同正盐的读法。,Mixed salt=Cation+cation+anionFor example:NaKSO3:Sodium potassium sulfite CaNH4PO4:Calcium ammonium phosphate AgLiCO3 Silver lithium carbonate NaNH4SO4 Sodium ammonium sulfate KNaCO3:potassuim sodium carbonate NaNH4HPO4:sodium ammo

20、nium hydrogenphosphate,7.5 水合盐：结晶水读做water或hydrate,如 AlCl36H2O:aluminum chloride 6-water 或 aluminum chloride hexahydrate AlK(SO4)212H2O:aluminium potassium sulfate 12-water,8.Acids8.1 Per-,hydro-,normal acid(its salt-ate,-ide),Acid=Central elements root-ic+acid For example:H2CO3 Carbonic acid H2SO4 S

21、ulfuric acid H3PO4 Phosphoric acid HNO3 Nitric acid HClO4 Perchloric acid HCl Hydrochloric acid,8.2 Meta-and hypo-acid(its salt-ite),Acid=Central elements root-ous+acid For example:H2SO3 Sulfurous acid H3PO3 Phosphorous acid HNO2 Nitrous acid HClO Hypochlorous acid HClO2 Chlorous acid,命名时先命名阳离子部分，最后

22、命名阴离子部分，阴离子配体以字母顺序列出，中心阳离子价态一般以罗马数字在名称后标出。KBF4 potassium tetrafluoroborate(III)K4Fe(CN)6 potassium hexacyanoferrate(II)Cu(NH3)4SO4 Tetraamminecopper(II)sulfate Co(H2O)2(NH3)2(CO2)NO3 Diammine diaquacarbonatocobalt(III)nitrate,9.络合物的命名（Naming coordination complex）,9.1 Ligands(配体),9.1.1 Negative ions

23、as ligands Ligand=Elements root-o For example:CN-Cyano NO2-Nitro F-Fluoro NO3-Nitrato Cl-Chloro CO32-Carbonato Br-Bromo CH3COO-Acetato O2-Oxo H-Hydrido OH-Hydroxo-O2CCO2-Oxalato,9.1.2 Neutral molecules as ligand,Ligand=Radical name For example:NH3 Ammine CO Carbonyl H2O Aqua CH3NH2 Methylamine H2NCC

24、NH2 Ethylenediamine,9.2 Complex ions,9.1 Neutral complex or complex ions with positive charge Complex ion=n-Ligand-metal ion(N)For example:Ag(NH3)2+Diamminesilver(I)Cu(NH3)42+Tetraamminecopper(II)Co(NH3)3(NO2)3 Triamminetrinitrocobalt(III),9.2 Complex ions with negative charge,Complex ion=n-Ligand-m

25、etals root-ate(N)For example:Fe(CN)64-Hexafluoroferrate(II)BF4-Tetrafluoroborate(III)AlF63-Hexafluoroaluminate(III)AuCl4-Tetrachloroaurate(III,9.3 Naming complex,Complex=Cation+anion For example:LiAlH4 Lithium tetrahydroaluminate(III)Ag(NH3)2Cl Diamminesilver(I)chloride K4Fe(CN)6 Potassium hexacyano

26、ferrate(II)Cu(NH3)4SO4 Tetraamminecopper(II)sulfate Ni(CO)4 Tetracarbonylnickel(0),常见配体的名称,10.Halide(卤化物):NH4Cl(Ammonium Chloride),CaF2(Calcium fluoride),NaBr(Potassium bromide),KI(Potassium Iodide)PCl3(Phosphorus trichloride),The Name of Cation+Halide,Inorganic ChemistryIntroduce:Inorganic chemistr

27、y is the study of the synthesis and behavior of inorganic and organometallic compounds.It has applications in every aspect of the chemical industryincluding catalysis,materials science,pigments,surfactants,coatings,medicine,fuel,and agriculture.,Inorganic chemists are employed in fields as diverse a

28、s the mining and microchip industries,environmental science,and education.Their work is based on understanding the behavior and the analogues for inorganic elements,and how these materials can be modified,separated or usedoften in product applications.It includes developing methods to recover metals

29、 from waste streams;employment as analytical chemists specializing in analysis of mined ores;performing research on the use of inorganic chemicals for treating soil.,Many inorganic chemists go into industry,but they are also at universities and in government labs.Inorganic chemists who work in gover

30、nment say their time is increasingly spent writing grant proposals and competing for a small pool of research money.Inorganic chemists compare their jobs to those of materials scientists and physicists.All three fields explore the relationship between physical properties and functions,but inorganic

31、chemistry is the most keenly focused on these properties at the molecular level.,Is a Creative Field The field of inorganic chemistry has traditionally been characterized by scientists with an artistic or creative flair.Many inorganic chemists say that they were drawn to the field in part by the pre

32、tty colors of the metals in the lab and by the interesting things that could be done in the lab.They often say the opportunities for creativity and inferential thinking are what they like best about their work.Describing themselves as tinkerers,inorganic chemists like putting things together and sol

33、ving problems and stress the importance of being detail oriented,precise,and persistent.Inorganic chemists describe their work as a constant challenge.The job changes all the time,says Steve Caldwell,an inorganic chemist working at Dow Chemical.Everyday there are a new set of issues and I have to de

34、termine which are the most important ones to work on first.Its definitely not a nine to five job.,Integrates Many Disciplines Inorganic chemistry,like many scientific fields,is becoming more interdisciplinary.Breakthroughs are anticipated in the interface between fields rather than in the more tradi

35、tional area.In the future,jobs will not be filled by super specialists,says Sauer,but by scientists with a broad base of knowledge.Even though a course of study like materials science or polymer science may appear to better position an individual for this interdisciplinary future,chemists in the fie

36、ld still strongly recommend getting a degree in inorganic chemistry.A degree in the basic discipline,will give a better understanding of bonding,valence,and orbital theory.,In addition,students are advised to take courses outside inorganic chemistry both to prepare themselves to integrate knowledge

37、towards problem solving as well as be flexible in todays tough job market.Dont just stick to inorganic chemistry,Sauer says.Learn inorganic chemistry and see how it applies in other areas.Caldwell adds,Starting out in inorganic chemistry doesnt mean thats what youll always do.I spent a few years doi

38、ng environmental research;there are always applications in related fields.,Exercise,H2SO4 HCl HNO3 HNO2HCN Na2S CuSO4 Fe(NO3)3 HClO4 KCN NH4Cl NaClONaOH Mn(OH)2 Fe2O3 P2O5H2O2 K2Cr2O7 Cu2(OH)2CO3CaHPO4 PtCl42-Ag(NH3)2Cl K4Fe(CN)6,Answer,H2SO4 sulfuric acid HCl hydrogen chloride or hydrochloric acid

39、HNO3 nitric acid HNO2 nitrous acid HCN hydrogen cyanide or hydrocyanic acid Na2S sodium sulfide CuSO4 copper(II)sulfate or cupric sulfate Fe(NO3)3 iron(III)nitrate or ferric nitrate HClO4 perchloric acid KCN potassium cyanide NH4Cl ammonium chloride,NaClO sodium hypochlorite NaOH sodium hydroxide Mn

40、(OH)2 Manganese(II)hydroxide Fe2O3 iron(III)oxide or ferric oxide P2O5 Diphosphorus pentoxide H2O2 hydrogen peroxide K2Cr2O7 potassium dichromate Cu2(OH)2CO3 Dicopper(II)dihydroxycarbonate CaHPO4 calcium hydrogen phosphate PtCl42-tetrachloroplatinum(II)Ag(NH3)2Cl Diamminesilver(I)chloride K4Fe(CN)6 Potassium hexacyanoferrate(II),Answer,