水泥专业外文翻译波特兰水泥.doc
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1、Portland cementPortland cement (often referred to as OPC, from Ordinary Portland Cement) is the most common type of cement in general use around the world because it is a basic ingredient of concrete, mortar, stucco and most non-specialty grout. It is a fine powder produced by grinding Portland ceme
2、nt clinker (more than 90%), a limited amount of calcium sulfate (which controls the set time) and up to 5% minor constituents as allowed by various standards such as the European Standard EN197.1 ASTM C 150 defines portland cement as hydraulic cement (cement that not only hardens by reacting with wa
3、ter but also forms a water-resistant product) produced by pulverizing clinkers consisting essentially of hydraulic calcium silicates, usually containing one or more of the forms of calcium sulfate as an inter ground addition. Clinkers are nodules (diameters: 0.2-1.0inch 525mm) of a sintered material
4、 that is produced when a raw mixture of predetermined composition is heated to high temperature. The low cost and widespread availability of the limestone, shales, and other naturally occurring materials make portland cement one of the lowest-cost materials widely used over the last century througho
5、ut the world. Concrete becomes one of the most versatile construction materials available in the world. Portland cement clinker is made by heating, in a kiln, a homogeneous mixture of raw materials to a sintering temperature, which is about 1450 C for modern cements. The aluminium oxide and iron oxi
6、de are present as a flux and contribute little to the strength. For special cements, such as Low Heat (LH) and Sulfate Resistant (SR) types, it is necessary to limit the amount of tricalcium aluminate (3CaO.Al2O3) formed. The major raw material for the clinker-making is usually limestone (CaCO3) mix
7、ed with a second material containing clay as source of alumino-silicate. Normally, an impure limestone which contains clay or SiO2 is used. The CaCO3 content of these limestones can be as low as 80%. Second raw materials (materials in the rawmix other than limestone) depend on the purity of the lime
8、stone. Some of the second raw materials used are: clay, shale, sand, iron ore, bauxite, fly ash and slag. When a cement kiln is fired by coal, the ash of the coal acts as a secondary raw material History Portland cement was developed from natural cements made in Britain in the early part of the nine
9、teenth century, and its name is derived from its similarity to Portland stone, a type of building stone that was quarried on the Isle of Portland in Dorset, England. The Portland cement is considered to originate from Joseph Aspdin, a British bricklayer from Leeds. It was one of his employees (Isaac
10、 Johnson), however, who developed the production technique, which resulted in a more fast-hardening cement with a higher compressive strength. This process was patented in 1824. His cement was an artificial cement similar in properties to the material known as Roman cement (patented in 1796 by James
11、 Parker) and his process was similar to that patented in 1822 and used since 1811 by James Frost who called his cement British Cement. The name Portland cement is also recorded in a directory published in 1823 being associated with a William Lockwood, Dave Stewart, and possibly others.Aspdins son Wi
12、lliam, in 1843, made an improved version of this cement and he initially called it Patent Portland cement although he had no patent. In 1848 William Aspdin further improved his cement and in 1853 he moved to Germany where he was involved in cement making. Many people have claimed to have made the fi
13、rst Portland cement in the modern sense, but it is generally accepted that it was first manufactured by William Aspdin at Northfleet, England in about 1842. The German Government issued a standard on Portland cement in 1878. ProductionThere are three fundamental stages in the production of Portland
14、cement:1. Preparation of the raw mixture 2. Production of the clinker 3. Preparation of the cement To simplify the complex chemical formulae which describe the compounds present in cement, a cement chemist notation was invented. This notation reflects the fact that most of the elements are present i
15、n their highest oxidation state, and chemical analyses of cement are expressed as mass percent of these notional oxidesRawmix preparationThe raw materials for Portland cement production are a mixture of minerals containing calcium oxide, silicon oxide, aluminium oxide, ferric oxide, and magnesium ox
16、ide, as fine powder in the Dry process or in the form of a slurry in the Wet process. The raw materials are usually quarried from local rock, which in some places is already practically the desired composition and in other places requires the addition of clay and limestone, as well as iron ore, baux
17、ite or recycled materials. The individual raw materials are first crushed, typically to below 50mm. Formation of clinkerThe raw mixture is heated in a cement kiln, a slowly rotating and sloped cylinder, with temperatures increasing over the length of the cylinder up to a peak temperature of 1400-145
18、0 C. A complex succession of chemical reactions takes place (see cement kiln) as the temperature rises. The peak temperature is regulated so that the product contains sintered but not fused lumps. Sintering consists of the melting of 25-30% of the mass of the material. The resulting liquid draws the
19、 remaining solid particles together by surface tension and acts as a solvent for the final chemical reaction in which alite is formed. Too low a temperature causes insufficient sintering and incomplete reaction, but too high a temperature results in a molten mass or glass, destruction of the kiln li
20、ning, and waste of fuel. When all goes according to plan, the resulting material is clinker. On cooling, it is conveyed to storage. Some effort is usually made to blend the clinker because, although the chemistry of the rawmix may have been tightly controlled, the kiln process potentially introduces
21、 new sources of chemical variability. The clinker can be stored for a number of years before use. Prolonged exposure to water decreases the reactivity of cement produced from weathered clinker.The enthalpy of formation of clinker from calcium carbonate and clay minerals is about 1500 to 1700 kJ/kg.
22、However, because of heat loss during production, actual values can be much higher. The high energy requirements and the release of significant amounts of carbon dioxide makes cement production a concern for global warming.Cement grindingIn order to achieve the desired setting qualities in the finish
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