Restricted Substances List(RSL) ppt.ppt

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1、,TV SD,限制物质解析和应对,Management Of The Restricted Substances,限用物质Restricted Substances,偶氮染料AZO邻苯二甲酸酯Phthalate有机锡化合物OTC镍释放Nickel Release铅Lead镉Cadmium汞Mercury其它重金属Other Heavy Metals多环芳香烃PAHs壬基酚和辛基酚NP&OP壬基酚/辛基酚聚氧乙烯醚NPEO&OPEO五氯苯酚和四氯苯酚PCP&TeCP邻苯基苯酚OPP,全氟辛烷磺酸/盐PFOS&PFOA富马酸二甲酯DMFuN,N-二甲基甲酰胺DMFa甲酰胺Formamide苯乙酮及

2、2-苯基-2-丙醇Acetophenone&2-phenyl-2-propanol六价铬Cr(VI)短链氯化石蜡SCCP甲醛FormaldehydepH值pH氯化有机载体COC阻燃剂Flame Retardant杀虫剂PesticideREACH高关注物质SVHC,偶氮染料AZO-Dye,什么是偶氮染料What is it?偶氮染料（AZO）是指偶氮基(-N=N-)两端连接芳基的一类有机化合物 Banned Dyes having one or several azo group(-N=N-)bound with aromatic compounds.潜在的健康危害:Potential hea

3、lth hazard:所列出的芳香胺是通过偶氮染料的裂解形成的，这些芳香胺是潜在的或已证明是致癌物质 The listed Aryl amines formed through cleavage from azo colorants are potential or proven to be carcinogenic.常见于Commonly found in:染色纺织品服装，皮革和鞋类。用于获得强烈和鲜艳的色彩以及某些特定的色调。Dyed textiles,apparel,leather and footwear.Used to achieve intense and bright color

4、s and to get certain specific shades.,使用偶氮染料的优点 Advantages of Azo Dyes:-在工业制程上是可作多种用途且容易使用之染料 Industrial production very versatile and easy-便宜 Cheap in the market-具有高消光性，及具有高吸收光的特性 High“molar extinction”,high absorption of light,只要少量就可达到制造者所要求的光亮和颜色(尤其是使用在皮件上)Relatively low amount necessary to achie

5、ve intense,bright colors(especially on leather!),为什么要用偶氮染料Why Azo dye used?,欧盟REACH附录17（先前为2002/61/EC）EU REACH EC(No.)1907/2006 Annex XVII(formerly known as directive 2002/61/EC)要求requirement:不能使用含有22 种违禁芳香胺的偶氮染料 Azo dyes contain 22 forbidden amines are not allowed to use,欧洲有关偶氮染料的要求EU Requirement o

6、n AZO dye,OEKO-TEX Standard 100对偶氮的要求 OEKO-TEX Standard 100 Requirement on AZO dye要求requirement:不能使用含有24 种违禁芳香胺的偶氮染料,每一种禁用的芳香胺不能超过20mg/kg Azo dyes contain 24 forbidden amines are not allowed to use,Each forbidden amine cannot exceed 20ppmGB 18401对偶氮染料的要求(同OEKO-TEX Standard 100)GB 18401 Requirement o

7、n AZO dye(same as OEKO-TEX standard 100),有关偶氮染料的要求Requirement on AZO dye,适用范围Scope-衣服，床上用品，毛巾，假发，帽子，尿布和其他卫生用品、睡袋，-clothing,bedding,towels,hairpieces,wigs,hats,nappies and other sanitary items,sleeping bags-鞋袜，手套，手表带，手提包，皮包或钱包，行李箱，座椅套，颈挂式皮包，-纺织制或皮制玩具和带有纺织或皮制衣物的玩具，-footwear,gloves,wristwatch straps,ha

8、ndbags,purses/wallets,briefcases,chair covers,purses worn round the neck,-供消费者使用的纱线和织物。-textile or leather toys and toys which include textile or leather garments,-yarn and fabrics intended for use by the final consumer.,不要使用禁用的偶氮染料Do not use Forbidden Azo Dyes,有关偶氮染料的要求Requirement on AZO dye,邻苯二甲酸酯

9、Phthalate,什么是邻苯二甲酸酯What is it?Phthalates 是邻苯二甲酸酯类，添加到塑料中可提高塑料弹性，透明度，耐久性及寿命。Phthalates are the esters of phthalic acids and its compounds added to plastics to increase flexibility transparency,durability,and longevity潜在的健康危害Potential health hazard:当幼儿在吸吮或咀嚼塑料的时候，Phthalates 会从塑料中迁移至他们的身体中，而邻苯二甲酸酯为可 疑致

10、癌物质以及会扰乱荷尔蒙体系。Phthalates can migrate from a plastic into the body of a child when he/she sucks or chews on the plastic.They are suspected to be carcinogenic and disturb the hormone system.常见于Commonly found in:纺织品，服装及鞋类中的弹性塑料部件，装饰及丝印。Flexible plastic components,trims and screen prints in textiles,app

11、arel and footwear,欧盟关于邻苯二甲酸酯的要求EU Requirement on Phthalate,欧盟REACH附录17（先前称为2005/84/EC）EU REACH EC(No.)1907/2006 Annex XVII(formerly known as directive 2005/84/EC)要求Requirement:DBP+BBP+DEHP:0.1%DNOP+DINP+DIDP:0.1%欧盟REACH SVHC候选清单 EU REACH EC(No.)1907/2006 SVHCs Candidate list要求Requirement:DEHP,DBP,BB

12、P,DiBP,DIHP,DHNUP:0.1%each of whole product,邻苯二甲酸酯的要求 Phthalate Requirement,CPSIA对邻苯二甲酸酯的要求CPSIA Phthalate Requirement,邻苯二甲酸酯的要求Phthalate Requirement,OEKO-TEX Standard 100对邻苯二甲酸酯的要求：OEKO-TEX Standard 100 Phthalate Requirement:Baby婴儿:7P（DEHP+DBP+BBP+DIBP+DNOP+DINP+DIDP）0.1%Other其它:4P（DEHP+BBP+DBP+DIB

13、P）0.1%加州65对时尚配件中邻苯二甲酸酯的要求：Phthalate requirements to all fashion accessories California Prop 65：时尚配件中各个可接触的组件中，要求各DEHP，BBP，DBP最大含量等于或低于1000ppm。Maximum concentration,by weight,of DEHP,BBP and DBP,each,of 1000ppm or less,in each Accessible Component of the Fashion Accessories.时尚配件指的是：皮夹,手提包，钱包，手袋和背包,腰带

14、,鞋,服装，包括手套和帽子,首饰,钥匙包，钥匙链，钥匙扣,箱包附袋，证件夹,箱包坠饰，拉链的拉扣,眼镜盒,移动电子设备的外套/盒子（如电话，照相机，MP3，CDs/DVDs以及手提电脑）等。,有机锡化合物Organo-tin Compounds,什么是有机锡What is it?有机锡或烷基锡化合物是锡和碳氢化合物的碳元素直接结合所形成的金属有机化合物Organo-tin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituent.潜在的健康危害Potential health

15、hazard:有机锡化合物为可疑的内分泌干扰物。Organo tin compounds are suspected to be endocrine disrupters.常见于Commonly found in:塑料，油墨，涂料和传热材料。三丁基锡氧化物是一种木材防腐剂，三丁基锡是一种海洋防生物污染剂。Plastics,inks,paints and heat transfer material.Tri butyl-tin oxide is a wood preservative.Tri-butyl tin is a marine anti-biofouling agents.,OTC法规背

16、景Background,2000年1月德国电视播报市场上的足球衣被发现含有 TBT 三丁基锡，当地政府也针对这件事情调查市面上的足球衣 In Jan 2000,a German TV broadcast reported that a soccer jersey found to contain TBT.The local Government also investigated the soccer jerseys in market.,TBT 的法规是由德国政府发起TBT regulation was found by German Government,批发商要求销售德国市场的产品必须是

17、不含TBT 的Distributors required the product in Germany must not contain TBT,什么是OTC？What is OTC?,在化学方面，有机锡化合物是由Sn与有机取代基R所组成的 Chemically,Organo-tin compounds consist of tin(Sn)and organic substituents“R”.化学结构如下 chemical structure：,R=Butyl(C4H9),see next chart=Octyl(C8H17)=Phenyl(C6H5),根据含有一、二、三或四个R(烷基)，分

18、别称为Mono,Di,Tri或Tetra有机锡化合物。Depending on whether there are one,two,three or four Rs,they are called Mono-,Di-,Tri-or Tetra-organic-tin-compounds,respectively.,什么是OTC？What is OTC?,1 稳定剂/催化剂 2 制药与化学工业的中间产物 stabilizer/catalyst Intermediates in Chemical and Pharmaceutical 3 除草剂 4 水溶性漆罐内保存剂 Herbicides In-

19、Can Preservation of colorant container 5 船舶之抗腐蚀漆 6 木材之防腐剂 Anti-fouling paint for ships Wood Preservatives,OTC的用途Usage of OTC,DBT与MBT被使用于各种聚合材料中的催化剂与稳定剂 DBT(and also MBT)are used as catalyst and stabilizer in a variety of polymeric materials 于皮革工业中用作涂布PVC，硅树脂和PU的催化剂as catalyst in coating with PVC,sil

20、icones and PUR(leather industry!)使用抗腐蚀剂防止甲壳类及藻类生物附着在船体 anti-fouling agent to repel barnacles and weeds from ships木材之防腐剂 wood preservative废水处理 waste water treatment农业之杀虫、杀菌剂 biocide,fungicide in agriculture卫生的密封材质 in sanitary sealing materialsMBT与DBT作用不纯物质 as impurity in substances containing MBT and

21、 DBT!,OTC的用途Usage of OTC,有机锡化合物Organo-tin Compounds,“儿童雨衣中激素干扰物”“Hormone disruptors in Children-Rainwear”,“如同港口废弃污泥一样有毒的儿童夹克”“Children jackets as poisonous as harbour waste sludge”,Source:German newspaper“Hamburg Morgen Post”23 October 2001,EU Regulation on OTC欧盟关于有机锡的法规,欧盟REACH附录17(原2009/425/EC)REA

22、CH EC(No)1907/2006 Annex XVII(formerly known as 2009/425/EC)要求Requirement:限值:要求三丁基锡，三苯基锡，三环已基锡，二丁基锡，二辛基锡小于0.1%（以锡含量计）Limit:TBT,TPhT,TCyT,DBT,DOT0.1%by weight of tin in the article,or part thereof,海洋杀生剂,Requirement on OTC关于有机锡的要求,OEKO-TEX Standard 100对有机锡的要求 OEKO-TEX Standard 100 requirement on OTC,我

23、们的测试能力Our Test Capabilities on OTC:MBT(一丁基锡），MOT（一辛基锡），DBT（二丁基锡），DOT（二辛基锡），TBT（三丁基锡），TPhT（三苯基锡）,TCyT（三环已基锡）,TeBT（四丁基锡）报告限Reporting Limit：0.025mg/kg,镍Nickel,什么是镍What is it？自然界中的镍(Ni)的蕴藏丰富，与其它金属结合形成合金可以提高硬度和抗腐蚀性。It is an abundant metal combined with other metals to make alloys with increased hardness

24、and resistance to corrosion.潜在的健康危害Potential health hazard：镍及其化合物为可疑致癌物，并导致人类过敏。Nickel and its compounds are reasonably anticipated to be carcinogens.It can cause allergenic reaction to human beings.常见于Commonly found in：服装，纺织品及鞋类中的金属部件，如饰片，金属纽扣，拉链等。Metal parts in apparel,textiles and footwear such a

25、s snaps,metal buttons,zippers etc.,欧盟REACH附录17(原94/27/EC)REACH EC(No)1907/2006 Annex XVII(formerly known as 94/27/EC)要求Requirement:,(1)在身上打洞穿戴之产品 Body-Piercing Items-如金属品是直接穿过耳朵或身体某些部位的物品，则镍含量不可超过 0.2 微克/平方厘米/星期Metallic items which are inserted into pierced ears and other pierced parts of the human

26、body must not release nickel exceeding 0.2 g/cm2/week,欧洲关于镍释放的法规EU Regulation on Nickel Release,Table of Content 目錄,(2)与皮肤有直接和长期接触皮肤之物品 Products with direct and prolonged skin contact-耳环、项链、手镯、手链、脚踝链、戒指、手表、表带和表链 Ear rings,necklaces,bracelets and chains,anklets,finger rings,wrist-watch cases,watch st

27、raps and tighteners-各种使用在成衣上的铆钉扣、铆钉、拉链和其它金属 rivet buttons,tighteners,rivets,zippers and metal marks,when these are used in garments-镍释放量每星期不超过 0.5 微克/平方厘米/星期Rate of nickel release must not exceed 0.5 ug/cm2/week.,欧洲关于镍释放的法规EU Regulation on Nickel Release,Table of Content 目錄,(3)表面镀有外层的产品Products with

28、 Outer Coating-第 2 大类之产品若表面镀上无镍的表层，必须保证产品在正常使用的情况下，经过二年後，镍释放量也不会高於每星期 0.5 微克/平方厘米 For products such as those defined in clause 2 which have a non-nickel outer coating the rate of nickel release must not exceed 0.5g/cm2/week for a period of at least two years of normal use.-适用此类产品之测试方法如下 The required

29、 testing methods for this class of coated items are the following:i)模拟产品在常规下两年後受磨损和侵蚀的状况，测試表面镀有外层的产品镍之释放量，此测试方法为 EN 12472 Method for the simulation of wear and corrosion for the detection of nickel release from coated items,EN 12472ii)镍释放量则依 EN 1811定量分析法 Quantification of Nickel release according to

30、 EN 1811:1999,欧洲关于镍释放的法规EU Regulation on Nickel Release,六价铬Cr(VI),什么是六价铬What is it？自然界中铬的主要存在形态有三种-Cr(0)，Cr(III)及Cr(VI)。Cr(III)是最稳定的形态，Cr(0)和Cr(VI)是极其稀少的。Chromium is a naturally occurring metal that can exist in three main forms Chromium(0),Chromium(III),and Chromium(VI).Cr(III)is the most stable fo

31、rm,while Cr(0)and Cr(VI)are quite rare.潜在的健康危害Potential health hazard:六价铬及含有六价铬的化合物是致癌物质，也是一种防腐蚀剂。Cr(VI)and certain Cr(VI)containing compounds are known to be carcinogens.It is also corrosive in nature.常见于Commonly found in:纺织品，服装，皮革及鞋类。六价铬通常与塑料，颜料和鞣制皮革联系在一起。Textiles,apparel,leather,and footwear.Chro

32、mium may be associated with plastics,pigments,and tanned leather,全世界百分之八十至九十的皮件在制革时使用铬 80-90%of leather products worldwide chrome tanned:这是世界上最便利的技术 convenient technology all over the world 具有极优的特性，很难有其它制皮的方法可达到如此好的效果 Excellent product properties,difficult to achieve by alternative tanning processes

33、一次浸泡 One-bath Chrome Tanning 含有三价铬的制皮浴是藉化学反应来处理毛皮和兽皮一次浸泡Tanning bath contains Chrome(III),which by chemical reaction tans the pelts,hides etc.两次浸泡 Two-bath Chrome Tanning 约有 10%使用此方法About 10%of Chrome Tanning worldwide is two-bath tanning步骤一:将产品浸泡於六价铬中Products are soaked with Chrome(VI)步骤二:经化学反应六价铬降

34、低为三价附 注:成品可含有三价铬，但不能含有六价铬 Chrome(VI)is reduced by chemical reaction to Chrome(III).(Chrome(VI)has no tanning effect).,六价铬Cr(VI),欧盟关于六价铬的要求EU Requirement on Cr(VI),法规 Regulation:德国 30 LMBG 共同的限定量:3 mg/kgA legal regulation is being prepared=Germany 30 LMBG其它欧盟国家无明确之规定No explicit regulations in other E

35、U countries 六价铬的来源 Sources of Chrome VI 以铬使生皮成为具有柔软与耐用性的皮革 Chrome tanning of leather 纺织类经过铬媒染剂染色 Chrome mordant dyeing of textiles 需测试之材料-皮革 leather-纺织类很少会有 Rare to find CrVI in textiles,六价铬的来源 Sources of Chromium VI,两次浸泡法 Two-Bath Tanning如果此制程未正确地执行，一旦六价铬未完全降低为三价铬，那麽六价铬将残留在皮件上If the two-bath tannin

36、g process is not carried out properly,residual Chrome(VI)remains on the leather 一次浸泡法 One-Bath Tanning三价铬能化学氧化成六价铬，这个过程是由碱性状态所促成，例如 Chrome(III)can be chemically oxidized to Chrome(VI),the process is favoured by alkaline conditions:-制程中使用氨来处理皮件(氨属碱性，用来中和酸性的皮)leather treatment with Ammonia(alkaline co

37、ndition!)-强碱胶应用于粘皮的部件 strong alkaline glues applied to leather parts,如过程中使用六价铬，则必须注意是否有六价铬残留在成品上 If two-bath tanning with Chrome(VI)is applied,care must be taken that there is no residual Chrome(VI)on the finished product.=State of the art of technical process!六价铬之形成是一种很复杂的化学反应，而依据研究所得，它可视下列要素而形成 Th

38、e Chrome(VI)formation is a complicated chemical reaction,according to research studies it can depend on the following factors:-降低使用助剂取而代之使用一般中性材料Replacement of normal neutralization materials by reducing agents reduced Chrome(VI)formation-像氨之类的强碱必需避免使用Strong alkalines such as Ammonia should be avoid

39、ed-制皮革使用之脂肪液化剂，如磺化油及亚硫酸盐鱼油会增加六价铬之形成 Fatliquoring agents like sulfonated and sulfited fish oils increase Chrome(VI)formation,如何符合规定 How to meet the requirements,如何符合规定 How to meet the requirements,六价铬之形成是一种很复杂的化学反应，而依据研究所得，它可视下列要素而形成 The Chrome(VI)formation is a complicated chemical reaction,accordin

40、g to research studies it can depend on the following factors:-含有不饱和脂肪酸的脂肪液化剂会增加六价铬，所以要慎选脂肪液是很重要的Fatliquoring agents containing unsaturated fatty acids increased Chrome(VI)formation.=Selection of Fatliquors is important-皮革再经过植物鞣料的处理，可降低皮革因曝露於高温与紫外线下六价铬的形成 Vegetable re-tanning agents decreased Chrome(

41、VI)formation in leathers exposed to extreme heat and UV radiation-皮革在经过植物鞣料及脂肪液之处理後，一旦初期未发现六价铬的形成，那麽再经过两个月的贮存也将不会有六价铬增加的情况发生 Leathers with re-tanning agents and fatliquors not increasing the Chrome(VI)formation in the fresh state,did not show increased Chrome(VI)levels after 2 month storage,严格控制鞣革程序

42、，避免六价铬残留在皮革当中Strictly control the tanning process and avoid CrVI reside in leather,六价铬Cr(VI),镉(Cd),什么是镉What is it?自然界中镉的稳定价态是二价，呈青白色且不易腐蚀或生锈。It is a naturally occurring and abundant bluish-white bivalent metal that does not easily corrode(rust).潜在的健康危害Potential health hazard:镉及其化合物具有致癌性。Cadmium and

43、its compounds are carcinogenic in nature.常见于Commonly found in:纺织品，服装和鞋类中。镉通常用作塑料的热稳定剂，颜料（尤其红，橙，黄和绿色），作为金属照相胶卷和电池表面的涂层。Textiles,apparel and footwear,cadmium may be associated with plastics(as a heat stabilizer),pigments(particularly red,orange,yellow and green),as a surface coating layer for metals p

44、hotographic films and batteries.,欧盟关于镉的法规EU Regulation on Cadmium,欧盟REACH附录17(原91/338/EC)REACH EC(No)1907/2006 Annex XVII(formerly known as 91/338/EEC)要求Requirement:塑料/涂层中镉含量不能超过100mg/kg Less than 0.01%by weight(expressed as Cd metal)of the plastic material 油漆中不能使用（但是锌含量超过10%的油漆中，Cd的限量为0.01%.Banned

45、in Paints and varnishes except Paints with a zinc content 10%by weight may contain Cd(expressed as Cd metal)in a concentration 0.1%by weight.,关于镉的要求 Requirement on Cadmium,OEKO-TEX Standard 100关于镉的要求 OEKO-TEX Standard 100 Requirement on Cadmium 总镉限值Requirement on total cadmium content:婴儿Baby：50mg/kg

46、 其它Other:100mg/kg镉迁移限制Requirement on Extractable Heavy MetalsExtractable Cd Content:0.1mg/kg,汞(Hg),什么是汞What is it?汞也称为水银，是常温常压下唯一的液态金属。Mercury is known as quick silver.Mercury is the only metal that is liquid at standard condition of temperature and pressure.潜在的健康危害Potential health hazard:汞中毒分慢性及急性两

47、种，如暴露在汞蒸气里，一个比较低的浓度0.742 g/m3就能引起震颤和认知能力受损以及睡眠障碍。如果长期的暴露，微小的震颤可能就会上升为肌肉震颤。Mercury can cause both chronic and acute poisoning.Exposure to mercury vapors,even at low concentrations in the range 0.742 g/m3,can cause tremors,impaired cognitive skills,and sleep disturbance.On continuous exposure,a fine t

48、remor develops and may escalate to violent muscular spasms.常见于Commonly found in:某些类型电解槽的电极，电池（汞电池），氢氧化钠和液氯生产，掌上游戏机，催化剂，某些类型的杀虫剂。氧化汞和硫化汞也常用于彩色油漆和染料纹身。用于纯棉纱线/面料洗刷的氢氧化钠中可能含有汞。Electrodes in some types of electrolysis,batteries(mercury cells),sodium hydroxide and chlorine production,handheld games,cataly

49、sts,insecticides.Mercuric oxide and mercuric sulphide are also commonly used in colour paints and tattoo dyes.Sodium hydroxide is used for scouring of cotton yarns/fabrics which can contain mercury.,关于汞 的要求Requirement on Hg,欧盟关于电子电器产品的RoHS指令2002/95/EC EU directive 2002/95/EC on the Restriction of th

50、e Use of Certain Hazardous Substances in Electrical and Electronic Equipment RoHS：1000 ppm on Pb,Hg,PBBs,PBDEs;100ppm on Cd。欧盟电池指令EU 2006/66/EC Battery directive 2006/66/EC欧盟REACH附录17European Union REACH Regulation(EC)No.1907/2006 Annex XVII.,铅(Pb),什么是铅What is it?它是一种天然柔软的延伸性金属。暴露在空气中为暗淡的浅灰色，对电池，燃料，