阿尔法烯烃的基础油 英力士ppt课件.ppt

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1、Improved Efficiency through the use of Special Viscosity Polyalphaolefins,Dr. Lionel D. Moore Associate Research Chemist, Technical Support PAO Base Fluids, INEOS OligomersMichel Sanchez PAO Customer Technical Service Manager, Europe, Middle East & North AfricaINEOS Oligomers,Engine Losses: 70%,Para

2、sitic Losses: 5%e.g. water pump, alternator, etc.,Drivetrain Losses: 5%,Idle Losses: 3%,Power to wheels: 17%,Fuel Energy: 100%,exhaust heat, friction, etc.,The auto industry ismoving to improve fuel efficiency.,Todays autos operateat 17-21% efficiency.,There is much potential for improvement.,Auto F

3、uel Efficiency Can Be Improved,Turbo-charger,Multi-speed transmission,Dual clutch trasmission,Belt CVT,Plug-inHybrid,Tailpipe emissions CO2,Hardware changes reduce CO2 Emissions,Electric,Low Viscosity Grades Improve Fuel Economy,Source: SAE J300 engine oil classification, April 2013,Constant Structu

4、re/Quality,Reduced Emissions,Low Friction,Low Volatility,Excellent Hydrolytic Stability,Excellent Low Temperature Properties,Compatible with other Base oils & Elastomers,High Thermal/Oxidative Stability,PAO,High Shear Stability,Allows Long Drain Intervals,PAOs well suited for Low Viscosity Oils,Poly

5、alphaolefins,Legislation has been instituted regulating all aspects of Greenhouse Gas Emissions,Raw Material Production,Recycling,Vehicle Operation,Legislation,Vehicle Manufacture,Fuel Economy MandatesEmission RestrictionsWeight Regulations,Source: ICCT,34.2 mpg by 201547 mpg by 2020,The Global Marc

6、h Towards Lower CO2 Emissions,Source: ICCT,54.4 mpg by 2025,The Global March Towards Lower CO2 Emissions,Source: ICCT,95g CO2/km for passenger carsby 2020 (69.1 mpg),The Global March Towards Lower CO2 Emissions,Cars of the future will incorporate,new materials and technologies,fuel efficient than th

7、e cars of today,that will make them even more,HDPE Fuel Tank,Grangemouth, UKGeel, BELillo, BENOH Tech Center, BESarralbe, FRKoeln, DEBamble, NOLavera, FRRosignano, IT,Carson, CA, US Gaines County, TX, US Alvin, TX, US LaPorte, TX, US,Low rolling Resistance tires,Mobil Alabama, USA,Antwerp BEGladbeck

8、 DEMarl DE,Sinopec INEOS JV,Ethanol,From refuse,Vero Beach Florida, US,Carbon Fiber Sheet,Boeing 787 uses carbon fiber composites,Composite frame & body panels,Lima Ohio, USALisle Illinois, USAGreen Lake, Texas USAPoint Comfort, Texas USALeague City, Texas USAHouston, Texas USATampico, Mexico,Kln, G

9、ermanyAntwerp, BelgiumSeal Sands , UK,Ulsan KoreaSeoul Korea,SingaporePasir Gudang Malaysia,THE WORLDS LARGEST INTEGRATED PRODUCER OF LOW AND HIGH VISCOSITY POLYALPHA- OLEFINS,Applications for PAO include: Multi-grade gear oils 7W-90 / 75W-140 Low viscosity transmission oils Industrial oils compress

10、or / gear / circulating Automotive oils 5W-20 / 0W-20 / 0W-16 Heavy Duty Diesel Oils Many others where high performance is required,INEOS Oligomers is the worlds largest merchant supplier of PAO Feluy, Belgium New PAO train added in 2009 15% debottleneck planned LaPorte, TX, USA 10% debottleneck com

11、pleted Additional trains / plants aligned with market requirements,INEOS to Expand Alphaolefin Supply,INEOS basic in LAO,Drilling Fluids,Detergents,Polyethylene comonomers,PAO feed stocks,LAOCH2=CH-(CH2)nCH3PAO,INEOS Expands Alphaolefin Supply New US plant build commenced Gulf Coast location, 350 KT

12、 500 KT Advantaged Ethylene (Shale Gas) Incremental expansions also planned at Joffre Canada and Feluy Belgium,INEOS Joffre, Canada,INEO Feluy, Belgium,Proposed Viscosity Grades Below SAE 20,Source: M Covitch, et al., Extending SAE J300 to Viscosity Grades below SAE 20,Boundary Lubrication,Hydrodyna

13、mic Lubrication,1/3 of engine losses,2/3 of engine losses,Fuel Economy Trend Moving from 10W-40 to 0W-16,Engine Oil Viscosity Grade,Source: J. Jeter, Honda, SAE Fuels and Lubricants Open Forum April 21, 2009,+ 1.5 %,Fuel EconomyImprovement,0W-20,5W-30,Sequence VI-D %Fuel Economyvs. Oil Viscosity Gra

14、de,Source: F Lockwood, Fuel Economy and Engine Durability, Ashland /Valvoline, April 2012,+ 1.5 %,Fully formulated oils using indicated PAO6 + PAO4, shear stable VII, TMP Ester, and European additive package,SAE 0W-20Range,6.9,15,6200,2.6,PAOs Easily Meet 0W-20 Viscometric Requirements,OW-20 Full Sy

15、nthetic,Group III oils need PAO to meet 0W-20 oil requirements,Source: H. E. Henderson, Lithcon PetroleumNPRA, Houston, TX, November 1-2, 2007,Group III oils need PAO to meet 0W-20 oil requirements,SAE 0W-20Range,6.9 9.3,15,6200,2.6,-,4 + 6 mm2/s Group III6.94 2.296,220Yes,4 + 6 mm2/s Group III6.40

16、2.145,997Yes,4 + 6 mm2/s Group III5.68 1.935,926-,6 + 8 mm2/s PAO6.95 2.315,465-,Group III has difficulty meeting 0W-15 requirements,Source: M. Covitch et. al., ibid,6200,2.3,5.6,0W-15,0W-15,High Temperature High Shear ViscosityHTHS 150C,Engine Wear,Engine Wear increases with decreasing HTHS,Source:

17、 B Zhmud, Tribology and Lubricant Technology, September 2011,Thinner oils reduce viscous losses but increase engine wear,Low wear (high HTHS),High wear (low HTHS),PAOs Decrease Engine Wear with Higher HTHS,PAOs have higher HTHS viscosity for a given CCS -35C viscosity than Group III oils,Engine Wear

18、,HTHS 150C,CCS -35C,HTHS 150C,KV 100C,PAO,Group III,Low wear,High wear,New grades aid formulation of Sub 0W-20 Oils,Can be combined with Group II/III mineral oils to optimize HTHS, CCS or Brookfield,Applications of Durasyn High Viscosity PAOs,INEOS proprietary catalyst technology plus1-Decene achiev

19、es improved properties: Consistent Backbone Architecture Improved viscosity index 180 Improved cold temperature properties Better properties than “conventional” decene-based high viscosity PAOs.,Durasyn High Viscosity Polyalphaolefins,New Property Map ofNext GenerationHigh Viscosity PAOs,INEOS High

20、Viscosity Polyalphaolefin Property Map,Higher Viscosity Index,Lower Volatility,100C Viscosity,Higher Thermal/Oxidative Stability,Lower Brookfield Viscosity,Conventional High Viscosity PAO,INEOS High Viscosity PAOs Allow Additive Packages to be fortified. Allow broader choice of higher viscosity, les

21、s volatile co-base oils. Make wide Multi-graded oils possible.,Durasyn High Viscosity Polyalphaolefins,75W-XX Multi-grades Offer:,Increased Fuel Economy Extended Drain Intervals Reduced Maintenance Reduced Down Time Less Oil Disposal,Durasyn High Viscosity Polyalphaolefins,75W-140 Demonstration Oils

22、*,* Fully formulated oils with PAO4, Ester, Additives,75W-140 with PAO8,75W-140 with PAO6,75W-140 with PAO4,75W-140 with PAO4 + Conventional Hi Vis,Durasyn 164 + INEOS High Vis,Durasyn 166 + INEOS High Vis,Durasyn 168 + INEOS High Vis,150,000 cP Limit,Brookfield Viscosity at -40C,75W-140 Oils using

23、PAO8 and INEOS Advanced Hi Vis PAOs,75W-140 with PAO4 + Conventional Hi Vis,75W-140 with PAO4,75W-140 with DS-146,75W-140 with PAO6,75W-140 with DS-148,75W-140 with PAO8,Durasyn 146 + INEOS High Vis,Durasyn 148 + INEOS High Vis,Brookfield Viscosity at -40C,150,000 cP Limit,Brookfield Advantage of IN

24、EOS 140 Series PAOs & Advanced Hi Vis,Decene: the best feed for High Viscosity PAOs,150,000 cPBrookfieldLimit,DS-180I214 VI,mPAO 1201 VI,mPAO 2198 VI,All fully formulated75W-140 Oils,Durasyn Polyalphaolefin Summary,INEOS Durasyn PAOs are Advanced Fluids tailored through molecular engineering. 160 Se

25、ries Decene-based, with high VI, excellent low temperature fluidity, and excellent shear stability.,Durasyn Polyalphaolefin Summary,INEOS Durasyn Low Viscosity PAOs Non-Decene PAOs -140 Series available with excellent properties. INEOS PAO offering gives Formulators more choice for optimized product

26、s with superior properties.,Durasyn Polyalphaolefin Summary,INEOS Durasyn Low Viscosity PAOs Sub 4 mm2/s - X Series PAOsAids formulation of SAE 0W-20 and lower. Balances HTHS, CCS, and Noack. Useful for transmission / driveline oils.,Durasyn Polyalphaolefin Summary,INEOS Durasyn High Viscosity PAOs Three grades (174I, 180R, 180I) with properties improved through advanced catalyst technology. Decene-based, with high VI, excellent low temperature fluidity, and excellent shear stability.,THANKYOU FOR YOUR ATTENTION,