55%代森联 5%吡唑醚菌酯WG MSDS（Nufarm Australia公司）.docx

55%代森联+5%唯哩醮菌酯WGMSDS(NufarmAustralia公司)CS:1.4.93age:!MaterialSafetyDataSheet4oflnfosafeNo3NUAQJuly2010ISSUEDbyNUfRMIssueDate:AER0EungicideProductNameClassifiedashazardous1.IDENTIFICATIONOFTHEMATERlA1.ANDSUPP1.IERProductNameAEROFungicideProductCode5365PrOdUCtTypeGroup11M3EungicideCoinpanyNameNUFAKMAUSTRA1.IA1.IMITED.(ABN80004377780)Address103-105PipeRoad1.avertonNorthVictoria3026AustraliaEmergencyTel.1800033498(24hrAustralia)TelehoneFaxNumberTel:+61392821000Fax:+6139282-1001RecommendedUseEorthecontrolofearlyandlate(Irish)blightinpotatoes,ear1yblightincapsicum,eggplant,peppersandtomatoes,downymildewinpoppiesandvariousdiseasesinmangoesasspecifiedintheDirectionsforUsetableonthelabel.OtherInformationThisMSDSdescribes,tothebestofourknowledge,thepropertiesoftheconcentratedproduct.Thephysicalpropertiesandsomeoftheassessmentsdonotapplytothepropertiesoftheproductonceithasbeendilutedforapplication.Acutehealtheffectsofthedilutedproductarelikelytobemuchlesssevere.2.HAZARDS1DENT11,1CAT1ONHazardClassificationClassifiedashazardousHAZARDOUSSUBSTANCE.NONDANGEROUSGOODS.HazardclassificationaccordingtothecriteriaofNOHSC.DangerousgoodsclassificationaccordingtotheAustraliaDangerousGoodsCode.RiskPhrase(三)ClassificdashazardousR22Harmfulifswallowed.R38Irritatingtoskin.SafetyPhrase(三)S13Keepawayfromfood,drinkandanimalfeedingstuffs.S2Keepoutofreachofchildren.S37Wearsuitablegloves.S46Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel.OtherInformationPoisonsScheduleS53.CompositionzinformationonIKGREDIENTSehemiCalCharacterizationSolidCASProportionNameIngrCdientS9006-42-2Metiram550gkgl75013-18-0Pyraclostrobin50gkgtheringredients(considerednon-hazardous)Balance4.FIRSTAIDMEASURESInhalationRemoveaffectedpersontofreshairuntilrecovered.Ifsymptomsdeveloporpersist,seekmedicaladvice.IngestionRinsemouthandthendrinkplentyofwater.Donotgiveanythingbymouthtoasemi-consciousorunconsciousperson.Obtainmedicaladvice.SkinWashaffectedareasthoroughlywithsoapandwater.Removecontaminatedclothingandlaunderbeforere-use.Ifirritationpersists,seekmedicaladvice.EyeIfineyes,holdeyelidsopenandwashWiIhcopiousamountsofwaterforatleast15minutes.Seekmedicaladvice.PrintDate:1/07/2010CS:1.4.93CS:1.4.93Page:2MaterialSafetyDataSheet4OfInfosafeNo3NUQJuly2010ISSUEDbyNUFRMIssueDate:AER0FungicideProductNameClassifiedasIiazardousFirstAidFacilitiesIfpoisoningoccurs,contactadoctororthePoisonsInformationCentre(Australia)on131126.AdvicetoDoctorTreatsymptomatically.Avoidgivingalcohol-maycausevomitingandshock.5.FIREFIGHTINGMEASURESSuitableExtinguishingMediaWaterfog,foam,carbondioxideordrychemical.AvoidstrongwaterJcts-airbornedustsmayformaflammabledustcloud.HazardsfromCombustionProductsMayemithazardoussmokeandfumesifinvolvedinfiresorexposedtoextremeheat.SpecialProtectiveEquipmentforfireFightersBrealhableairapparatusshouldbewornwhenfightingafireinwhichthisproductisinvolved.EmergencyActionincaseofFireIfexposedtofire,keepcontainercoolbysprayingwithwater.OtherInformationSTOPFIREWATERFROMENTERINGDRAINSORWATERBODIES.6.ACCIDENTA1.RE1.EASEMEASURESSPiuSDisposalRecovertheproductbysweepinguporvacuumingwithoutraisingdust.Collectspilledmaterial,wasteandwashwaterinsealableopen-toptypecontainersfordisposal.On-sitedisposalofconcentrateisnotacceptable.PersonaProtectionForappropriatepersonalprotectiveequipment(PPE),referSection8.7.HAND1.INGANDSTORAGEPrecautionsforSafeHandlingDoNOTcontaminatedams,riversorstreams,oranyotherwaterbodieswithpesticideorusedcontainers.Avoidgeneratingdustswhilehandlingtheproductandmixing.ConditionsforSafeStoragcStorcintheclosed,originalcontainerinacool,wellventilatedarea.Donotstoreforprolongedperiodsindirectsunlight.OtherInformationIwaysreadthelabelandanyattachedleafletbeforeuse.8.EXPOSURECONTRO1.SPERSON1.PROTECTIONNationaExposureStandardsNoexposurestandardshavebeenestablishedforthisproductbyWorksafeAustralia,however,theTWAexposurestandardfordustsnototherwisespecifiedis10mgm3.EngineeringControlsUseinawel1ve11tiIatedareaonly.Avoidgeneratingandinhalingdusts.RespiratoryProtectionIfdustsarepresent,wearaclassPldustmask.PersonalProtectiveEquipmentWhenopeningthecontainer,preparingsprayandusingthepreparedspraywearcottonoverallsbuttonedtotheneckandwristandawashablehat,elbow-IengthPVCglovesandgoggles.Re-entryperiod:Donotentertreatedareaunti1sprayhasdried.HygieneMeasuresAfteruseandbeforeeating,drinkingorsmoking,washhands,armsandfacethoroughlywithsoapandwater.Aftereachday'suse,WaShcontaminatedclothingandsafetyequipment.RequirementsConcerningSpecialTrainingCheckStateorTerritoryregulationsthatrequirepeoplewhousepesticidesintheirjoborbusinesstohavetrainingintheapplicationofthematerials.9.PHYSICA1.ANDCHEMICA1.PROPERTIESormSo1iClAppearanceBrowngranu1esOdourromaticodourSolubiIityinWaterDispersesinwater.pHValuc4.7(1%suspensioninwater)PrintDate:1/07/2010CS:1.4.93CS:1.4.93Pagc:3MaterialSafetyDataSheet4ofInfosafeNo3NUAQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedasHazardousVapourPressureO.OlmPa(metiram©20C);2.6x10-5mPa(pyraclostrobinQ20C)0ctanolWaterPartitionCoefficientKow1.ogPis0.3(metirampH7);3.99(pyrac1ostrobin)F1ammabi1ityDustmayformflammabledustcloud.Auto-IgnitionTemperaturel99C10.STABI1.ITYANDREACTIVITYChemicalStabilityStableundernormalconditions.IncompatibleMateriaIsAvoidcontactoftheproductwithstrongacidsandbases.HazardousPo1ymerizatiOnHazardouspolymerisationisnotpossible.11.TOXICO1.OGICA1.INFORMTIONToxico1ogyInformationNoharmfuleffectsareexpectediftheprecautionsonthelabelandthisMSDSarefollowed.InhalationMaycauseirritationtotherespiratorytract.Breathinginhighconcentrationsofdustsoraerosolsofthismaterialmaycauseheadache,nausea,dizzinessandweakness.IngestionPossiblesymptomsofexposureinclude:headache,nausea,dizzinessandweakness.Consumptionofalcoholincreasesthetoxiceffects.SkinMayirritatetheskin.EyeMayirritatetheeyes.ChronicEffectsBasedonavaiIablcdata,repeatedexposuresarenotanticipatedtocauseadditionalsignificantadverseeffects.AcuteToxicity-Oral1.D50(rat)500-2000mg/kgforasimiIarPormulationAcuteToxicity-Derma11.D5O(rat)2000mg/kgforasimilarformulationAcuteToxicity-Inhalation1.CSO(rat)(4hr)5.6mg/1forasimilarformuIationEyeIrritationMildeyeirritant.SkinIrritationMildskinirritant.OtherInformationTheAustralianAcceptableDailyIntake(.DI)formetiramforahumanis0.02mg/kg/day,setforthepublicfordaily,lifetimeexposure.ThisisbasedontheNOE1.of5mg/kg/day,lhe1eve1determinedtoshownoeffectsduringlongtermexposureforthemostsensitiveindicatorsandthemostsensitivespecies.(Ref:Comm.Dept,ofHealthandAgeingOfficeofChemicalSafety,*DI1.ist,December2008).DIforPyraclostrobinis0.03mg/kg/day,NOE1.3mg/kg/day.12.ECO1.OGICA1.INFoRMATIONPersistence/DegratlabiIityNotreadilybiodcgradab1e.KnownHarmfulEffectsontheEnvironmentTheproductisamarinepollutantforseatransport.OtherPrecautionsOonotcontaminatedams,waterwaysorsewerswiththisproductorthecontainerswhichhaveheldthisproduct.Environ.ProtectionSpraydriftcancausedamage,readthelabelformoreinformation.AcuteToxicity-FishToxictofish.I-C5O(96hr)forrainbowtroutisO.149mgl.Theabovedataisfortheformulatedproduct.AcuteToxicity-lgaeEC50(72hr)forPseudokirchneriel1asubcapitataisO.25mg/1forasimiIarformulation.AcuteToxicity-OtherOrganismsNottoxictobirds.Nottoxictobees.PrintDate:1/07/2010CS:1.4.93CS:1.4.93Page:4MaterialSafetyDataSheet4OfInfosafeNo3NUQJuly2010ISSUEDbyNUFARMIssueDate:AEROFungicideProductNameClassifiedashazardous13.DISPOSA1.CONSIDERATIONSProductDisposalOnsitedisposaloftheconcentratedproductisnotacceptable.Ideally,theproductshouldbeusedforitsintendedpurpose.Ifthereisaneedtodisposeoftheproduct,approachlocalauthoritieswhoholdperiodiccollectionsofunwantedchemicals(ChemClear),ContainerDisposa1Thorough1ywashouttheinnerandaddwashingstothespraytank.Disposeofwashedinnerandcardboardboxinlandfill.Ifnolandfillisavai!able,burythecontainersbe1ow500mminadisposalpitspecificallymarkedandsetupforthispurposeclearofwaterways,desirablevegetationandtreeroots.Emptycontainersandproductshou1dnotbeburnt.14.TRANSPORTINFORMATIONStorageandTransportConsidercdnondangerousforroadandrailtransport(inpackaging)bytheAustralianCodefortheTransportofDangerousGoodsbyRoadandRail.Rcf:X7;SPNo.AUOl.ForbulkshipmentsasClass9,useUN3077,HazChemcode2Z.UNNumber(SeaTransport)3077MOClass/PackingGroupClass9;PackingGroupIIIlMOMarinePollutantMarinepollutant.IMOProperShippingNamcENVIRONMENTAIXYHAZARDoUSSUBSTANCE,SO1.ID,N.0.S.(ContainsMetiramandPyraclostrobin)15.REGU1.ATORYINFORMATIONPoisonsScheduleSSPackaging1.abellingCAUTIONKEEPOUTOFREACHOFCHI1.DRENREADSAFETYDIRECTIONSBEFOREOPENINGORUSINGHazardCategoryHarmful,Irritant1AICS(Australia)AllofthecomponentsinthisproductarelistedontheAustralianInventoryofChemicalSubstances.16.OTHERINFORMATIONDateofpreparationorlastrevisionofMSDSRevised01/07/201OContactPersonZPointNormalHours:MrVolkerMaierPhone:+6139282100OAftcrHours:ShiftSupervisorPhone:1800033498RevisionsHighlighteclTheMSDSwasreviewed.Changesmadetosections:1-ProducttypeandRecommendedUse.OtherInformationRegisteredtrademarkofBSF.EndOfMSDS.CopyrightACOHSPty1.tdCopyrightinthesourcecodeoftheHTM1.,PDF,XM1.,XFOandanyotherelectronicfilesrenderedbyanInfosafesystemforInfosafeMSDSdisplayedistheintellectualpropertyofAcohsPty1.td.Copyrightinthelayout,presentationandappearanceofeachInfosafeMSDSdisplayedistheintellectualpropertyofcohsPty1.td.ThecompilationofMSDS,sdisplayedistheintellectualpropertyofAcohsPty1.td.CopyingofanyMSDSdisplayedispermittedforpersonaluseonlyandotherwiseisnotpcrmitted.InparticulartheMSDS,Sdisplayedcannotbecopiedforthepurposeofsaleorlicenceorforinc1usionaspartofacollectionofMSDSWithOUltheexpresswrittenconsentof