化学品安全及安全技术说明书Chemical_Safety_and_MSDS_(Rev).ppt

1,化学品安全及安全技术说明书Chemical Safety&Material Safety Data Sheet(MSDS),讲师Trainer：林青青 Lin Qingqing编制Author：林青青 Lin Qingqing修订 Reviser:林青青 Lin Qingqing修订次Rev:(Dec 2006)状态Status：当前 Current,审核 Reviewed by：Dr.Claas Juergens 批准 Approved by：,2,法规要求 Regulatory requirements化学品及其危害 Introduction of chemicals and the hazard安全标志 Safety sign运输标签 Transport label化学品安全技术说明书 Material Safety Data Sheet(MSDS)化学品的安全使用、处置和运输 The safety of usage,disposal and transport of chemicals,培训内容 Training schedule,3,通过此次培训，对一些法规要求及化学品的基本知识有所了解，并能够阅读化学品安全技术说明书。To increase the knowledge of the regulation requirements and the chemicals,be capable to read MSDS by this training.,培训目的 Training objective,4,我国的主要化学品管理法规及标准Main regulations and standards of chemicals management in China,中华人民共和国安全生产法 Safe Production Law of the Peoples Republic of China危险化学品安全管理条例 Regulation on control over DG chemicals工作场所安全使用化学品规定（170公约）Regulation on safely using chemicals in working area（170 pact）常用危险化学品的分类及标志（GB13690-1992）The classification and sign of dangerous chemicals in common use危险货物分类和品名编号（GB6944-2005）The classification and number of dangerous goods 危险货物品名表（GB12268-1990）The name list of dangerous goods化学品安全标签编写规定（GB15258-1999）Regulation on safety label 化学品安全技术说明书编写规定（GB16483-2000）Regulation on making MSDS,国内相关法规及标准 Related regulation,5,指各种化学元素、由元素组成的化合物及其混合物，无论是天然的或是人造的。Means all kinds of chemical element,compounds which constituted with element and compounds mixture,whether natural or manmade.,什么是化学品？What are chemicals?,6,固体：在室温下以固态形式存在的物质。如金属，塑料 Solids the materials exist as a solid form under the normal room temperature.e.g.metals,plastics液体：在室温下以液态形式存在的物质。如稀释剂 Liquids the materials exist as a liquid form under the normal room temperature.e.g.thinners气体：在室温下以气态形式存在的物质。如一氧化碳 Gases the materials exist as a gas form under the normal room temperature.e.g.carbon monoxide蒸气：液体由于温度、压力的改变形成空气中的微小液滴，正常状态下为液体。Vapours the liquid forms tiny liquid drops in the air because of the change of temperature and pressure,it will be liquid in normal condition.e.g.solvents烟：固体由于温度、压力的改变形成空气中的细小的固体颗粒。Smoke the solid forms tiny solid particle in the air because of the change of temperature and pressure.尘：室温下空气中的细小固体颗粒。Dust the tiny solid particle in the air under the normal room temperature.,存在形式 Existence forms,7,化学品中具有易燃、易爆、有毒、有害及有腐蚀特性，会对人员、设施、环境造成伤害或损害的化学品属危险化学品。The chemicals which have the characters of flammability,explosive,toxic,harmful and corrosive,and will cause hurt or damage to person,equipments and environment are dangerous chemicals.,危险化学品(一)Hazardous chemicals,8,常用危险化学品的分类及标志（GB13690-1992）“The classification and sign of dangerous goods in common use”第1类：爆炸品 class 1:explosive第2类：压缩气体和液化气体 class 2:compressed gas and liquefied gas第3类：易燃液体 class 3:flammable liquid第4类：易燃固体、自燃物品和遇湿易燃物品 class 4:flammable solid,substance liable to spontaneous combustion and substances flammable when wet第5类：氧化剂和过氧化物 class 5:oxidizing substances and peroxide第6类：有毒品 class 6:toxic第7类：放射性物品 class 7:radioactive substance第8类：腐蚀品 class 8:corrosive,危险化学品(二)Hazardous chemicals,9,BYC所用到的危险化学品 Examples in BYC,产品：finished products 苯 benzene甲苯 toluene甲酸 formic acid丙酸 propionic acid一甲胺 monomethylamine二甲胺 dimethylamine三甲胺 trimethylamine丙烯酸 acrylic acid丙烯酸甲酯 methyl acrylate丙烯酸乙酯 ethyl acrylate丙烯酸丁酯 butyl acrylate,原料：raw materials硫酸 sulfuric acid氢氧化钠 caustic soda氨（氨水、液氨）ammonia(ammonia water solution,ammonia liquid),危险化学品(三)Hazardous chemicals,10,一些化学品单独储存可能是安全的,但是如果和其他化学品接触时会变成危险品。Several chemicals are probably safe when storage separately,however they will be hazardous when contact with other chemicals.化学品的危害有：The hazard of chemicals are可燃 flammable有毒 toxic可爆 explosive腐蚀 caustic环境 environmental,化学品的危害 The hazard of chemicals,11,你的肺部：如果你吸入烟,雾,灰尘 Your lung:if you inhale smoke,fug and dust你的皮肤：液体或粉料接触或溅到皮肤上或眼睛里 Your skin:contact liquids or powder,spill to skin and eyes你的口：如果你接触化学品后吃东西 Your mouth:if you eat something after contacting chemicals意外吞入：化学品 Swallow accidentally:chemicals,化学品进入人体的途径 Routes of entry into body,12,使用化学品必须遵守的第一条规则是“知道你在和什么化学品打交道,并且知道如何保护自己和别人”The first rule of using chemicals must be observed is:You must know which chemicals you are working on,and how to protect yourself and others?,安全使用化学品？How to use chemicals safety?,13,安全标志 safety sign运输标签 transport label化学品安全技术说明书 material safety data sheet（MSDS),如何得到相关信息？Where to get information?,14,安全标志“safety sign”(GB2894-1996）安全标志使用导则“the usage guideline of safety signs”(GB16179-1996）BYC Portal:01-010-00-0-0-00-021 Safety signs 安全标志在哪里？Where are safety signs?公司/装置的入口处 the entrance of company/plant工作区域 working area装有化学品的管道、容器上 the pipeline and container with chemicals,安全标志 Safety sign,15,安全标志举例 Examples of safety sign(1),16,环保标志 Environment protect signs,废气排放口 Outlet of waste gas,当心危险固体废物 Caution hazardous waste solid,安全标志举例 Examples of safety sign(2),17,禁止标志 Prohibition sign,18,当心中毒Caution,toxic hazard,当心火灾易燃物质Danger of fire-Highly flammable materials,当心爆炸爆炸性物质Danger of explosion-Explosive materials,当心火灾氧化物Danger of fire-oxidizing materials,警告标志 Warning sign,19,必须戴安全帽和防护眼镜Must wear safety helmet and protective goggles,必须戴护耳器Must wear ear protector,必须戴眼部和脸部防护用品Must wear eye and face protection,必须加锁Must be locked,必须戴防毒面具Must wear gas defence mask,强制性标志 Mandatory sign,20,应急信息标志 Emergency information sign,21,危险化学品标志 Dangerous chemicals sign,22,举例Example,23,化学品安全标签编写规定(GB15258-1999）“The regulation of making chemicals safety label”(GB15258-1999）化学品安全标签包括物质名称、危险性标志、编号、警示词、危险性概述、安全措施、灭火方法、生产厂家、地址、电话、应急咨询电话、提示参阅 MSDS 等内容 The chemicals safety label contains:the name of substance,hazard sign,number,alarm words,hazard identification,safety measures,fire-fighting method,product company information(address,phone number,emergency consultation number),reminding of seeing MSDS,运输标签 Transport label,24,25,常用危险化学品标志-主标志 Main sign,26,常用危险化学品标志-副标志 Subsidiary sign,27,化学品安全技术说明书编写规定（GB16483-2000）“Regulation on making MSDS”化学品使用者获取有关化学品危害讯息和安全措施的来源 The source of hazard information and safety precautions of a chemical product for users化学品供应商向用户传达必要的化学品危害信息的工具 The tool for the chemical supplier to transfer essential hazard information of a chemical product to the recipient提供紧急响应的信息 Provide emergency response information管理工作场所中化学品的参考资料 The reference for management of hazardous chemicals in workplace操作工的安全培训 Training program of worker protection安全措施 Safety measures安全操作规程,化学品安全技术说明书（MSDS）,28,化学品安全技术说明书（MSDS）,29,以一份Documentum中公布的MSDS为例，详细说明。Take one MSDS which has published in BYC Documentum for example,introduce every part.BYC Portal/EHS/MSDS C00-7.5.1-00PSH-200 MSDS Management,举例Example:,30,C00-6.3.0-00GSH-201Guideline Information Card,信息卡Information card,31,R22 误吞对人体有害 Harmful by acute ingestionR24 沾及皮肤后会中毒 Toxic by acute skin absorptionR26 吸入会中剧毒 Very Toxic by acute inhalationR34 引致灼伤 Corrosive by acute eye/skin absorption R41 对眼睛造成严重损害 Irritant by acute eye absorptionR42 吸入可引起过敏 Sensitising by acute inhalationR45(1)引致癌症 Carcinogen by chronic exposureR46(1)可造成遗传性的基因损害 Mutagen by chronic exposureR47(1)可引致先天性缺陷 Teratogenic by chronic exposure,风险短语-举例 Risk phrase-example,32,S1 必须上锁 Keep locked upS2 不要让儿童接触 Keep out of reach of childrenS3 置于阴凉处 Keep in cool place S4 切勿放近住所 Keep away from living quartersS1/2 上锁保管并避免儿童接触 Keep locked up&out of reach of childrenS3/7 保持容器密闭并在阴凉处保存 Keep container tightly closed,in a cool well ventilated placeS3/9/14置于阴凉、通风处，并远离存放(由生产厂指明的不相容物质)Keep in a cool,well ventilated place away from(incompatible material to be indicated by manufacturer),安全短语-举例 Safety phrase-example,33,你知道危害和如何保护自己 know the hazard and how to protect yourself仅用于批准的用途 only use chemicals in the approved purpose储存适当 suitable storage the chemicals使用正确的个人防护用品 use correct personal protective equipments(PPE)不在使用化学品的区域饮食 not drink and eat in the area of using chemicals接触化学品后立即清洗 cleanout immediately after contacting chemicals,安全地使用化学品 Safety use chemicals,34,可以用个人防护用品来防护化学品危害 can use PPE to protect the chemicals hazard针对不同的化学品使用公司规定的个人防护用品 use PPE which are prescriptive by company according to different chemicals在使用前检查个人防护用品,确保无损坏 check PPE and make sure no disrepair before using如果有飞溅危险,则使用面罩或防护镜 use shield or goggles if there is the danger of splash使用适当的呼吸器防护灰尘,烟雾 use suitable air supplying to protect dust and fug在操作化学品时使用正确的手套 use correct gloves when working on chemicals使用后正确地清洁和储存个人防护用品 clean and storage PPE correctly after using不要把个人防护用品带回家 为什么要把危险带回家呢?not take PPE home why take danger home?,保护自己-个人防护用品 Protect yourself-PPE,35,每种化学品和容器都必须合适地处置 every chemical and container must be suitable disposed在彻底洗干净前,容器并不是真的“空”了 whether the container is empty as far as possible before being thoroughly cleaned根据环保法规要求处理使用过的容器 dispose the used container according to the request of environment protection regulation依照BYC管理程序处理未使用的化学品 dispose the untapped chemicals according to the BYC management procedure不要把未处理的化学品倒入水池、地表、雨水沟 dont pour the chemicals without disposal into pool,the earths surface and the channel of rain water,安全地处置化学品Safely disposal with chemicals,36,将不兼容的化学品分开储存 storage separately with un incompatible chemicals将易燃物的数量减少到最低 reduce the quantity of flammable substance to the least将易燃液体储存在批准的储存柜中 storage the flammable liquid in storage cabinets which are approved将酸单独储存在专用防火柜中，将有毒品单独储存在保险柜中 storage the acid separately in special fireproofing cabinets,storage the toxic material separately in strongbox不要将化学品储存在摆放食物的冰箱中 dont storage chemicals in the refrigerators which are used keeping foods不要将食物储存在摆放化学品的冰箱中 dont storage foods in the refrigerators which are used keeping chemicals,安全地储存化学品 Safety storage chemicals,37,执行相应的紧急行动计划 carry out relevant emergency response plan疏散人员 evacuate people隔离区域 不允许他人进入 separate areas not allowed others enter关闭火源和热源 close fire source and heat source只有受训人员才可以清理泄露物 only the person who received training can clear the leakage,如果发生紧急情况If any emergency case,38,知道你接触的是什么 know what you contacted知道MSDS在哪儿,知道如何使用 know where is MSDS and how to use如果有问题,向主管咨询 consult with director if any problem只有接受过培训的员工才可以使用化学品 only the person who received training can use chemicals确保所有容器都被标示 make sure all the containers have been marked使用正确的个人防护用品 use correct PPE将化学品储存在批准的区域 storage chemicals in approved areas立即汇报泄露和溢出 report immediately if any leakage and spillage正确地废弃化学品和容器 correctly dispose with chemicals and containers,小结 Summarize,39,结束 End,疑问?,40,谢谢!Thank you!,如有需求,请与CTS/S联系,